and M.S.: overall direction and design of project. and T.L.: collection and analysis of the X-ray imaging data. and A.J.R.: modelling of the IR data and structures. and G.C.: collection and analysis of synchrotron X-ray diffraction and IR spectroscopy data. and L.W.B.: syntheses, characterisation of MOF samples, measurements and analysis of xylene separation experiments. It is a measure of the difference in interactions of two analytes with the mobile and stationary phases, and therefore the difference in retention times (Eq. The separation factor (αi, j) of a column for substrate i and j is influenced by the column packing material and the eluent used. Details of conditions reported in literature examples are shown in Supplementary Table 9. Selectivities denoted by an asterisk were calculated from multicomponent liquid-phase adsorption experiments. (1) in the method section and selectivities were calculated from the ternary breakthrough curves (Eqs. The separation factors were calculated based on pulse chromatograms using Eq. A Comparison of separation factors calculated from chromatographic experiments b comparison of selectivity data calculated from breakthrough curves.
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